Surface-mount diodes in that package come with one diode, two diodes, both in series, or with cathodes on a common pin, or anodes on a common pin.
The board was laid out for one type, but the part that's "sideways" has the wrong pinout. It's turned the way you see it to satisfy the proper circuit hookup with the part they could get. Looks as if a diode with the correct pinout was not available.
Or maybe they flubbed the board layout for that part? We'll probably never know.
The circuit uses a diode with two junctions in series to double the temperature response you would get from a single diode. It's there to stabilize the regulated voltage over temperature changes.
A pair of 1N4148 generic diodes in series will work in place of that part, but the physical hookup will be awkward and fragile.
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