Chimney mounts can be used for a lot of things, CB antennas included. There are some aspects of it that you ought to be aware of before going to a lot of trouble. Chimneys come in all kinds of sizes/shapes and are made from a number of different things. I think it would be a very good idea to sort of evaluate your chimney before you get too far along, you know?
Plain old tin stove pipe, clay tile, 14 tons of brick and concrete? See where I'm going with that? You don't have to be a structural engineer, some common sense ought'a work, in general. If it gets to the point where you think that structural engineer might be needed to make a decision, I think I'd give it a 'pass'.
Is that chimney in use? That can be a deciding factor sometimes. Lots of nasty goop comes out'a them things, will it affect your antenna? Or how bad will it affect your antenna? Putting a fiberglass antenna/feed line/whatever over the top of a lit fire just ain't too 'swooft', you know? Metal ones too for that matter. (That ain't how "turning up the heat" is commonly meant with radio stuff.)
Metal straps are the most common method of securing a mount to a chimney. The more distance between that top and bottom strap tends to make the whole mess sturdier. It can also be carried to extremes. More of that common sense thingy. And just how easy is that chimney to get to? Used to be a chimney/smokestack at a local power house. Would have loved to have an antenna on top of it. If you think I'd climb that @#$ thing to put one up there, you are stone crazy! Common sense, or chicken? I don't care, not me!
Guying an antenna isn't a bad idea. Sometimes it isn't too practical for a number of reasons. You have to decide that one.
Is that all you have to consider if you're going to put an antenna on a chimney? No, but it ought'a give you some indication if it can work in your particular circumstances.
Have fun.
- 'Doc