Apologies! I missed the question wrapped up in there!
Short answer: Yes! Absolutely.
Longer answer: A lot depends on how you are going to use your SA.
If all you are going to do is get a display of the spectrum going, observe the cleanliness, go look at the 54 MHz trap setting.... it will absolutely work fine.
If, however, you are going to do more "value based" testing and measurement, the thing that you have to keep in mind is: everything you put in line has an insertion loss. That loss is ADDITIVE. So when you are looking at the display and actually measuring dB levels you have to take those insertion losses into account if you want to be more accurate. SO yes...it will all work.... but if you are counting on accurate measurements you have to take the individual losses of the adapter, the block, even the cables if you want to be spot on... into account.
[edited to add]
For instance if you have a 10 watt radio and your RF tap attenuates the sample tap by 40 dB, then 40 dBm - 40 db = 0dBm reaching the SA which is pretty good. However, if your DC block has 0.5 dB insertion loss and your pad adapter (number from thin air!) has 1.2 then you will actually be getting less signal at the SA.... - 1.7 dBm. You have to take that extra loss into account for the measurements to be precise.