Here is an option for those on AM who want to experiment with getting about twice the output from 18 volts the easy way. First understand that you are risking your transistors if you make a mistake with drive or carrier level and your amplifier has to have a few key things in place. Many can do this without modification. You are also likely to splash more because of IMD.
The amplifier has to be class C. That means the bases of the transistors are at DC ground trough the input transformers. The amp should have 2SC2879 transistors. The capacitors across the output transformers and transistor collectors should be no higher then 680 pf. If your amp fits this description you can probably run 18 volts. Some 16 volt electrolitics may get warm.
You need a 6 volt battery. The bigger it is the longer you can talk. Place this battery in series with the positive 12 volt line feeding your amp. You can use a 6 volt battery charger powered from a cigarette lighter 110 volt AC inverter to charge the 6 volt battery. You could also just use the battery if you're not talking long and take it home to charge.
The most important thing to consider in order to prevent transistor failure is drive level. The amp will require LESS drive then it did on 12 volts. Your radio should have a variable RF power control on it. Drive should never be turned up past the point where the carrier exceeds 25% of the max PEP. If you use a true RMS meter this point is when the meter still moves the slightest bit forward with modulation. Not backwards.
Lower drive will increase reliability. One quick mistake with too much drive will burn open the transistor junctions! The amp will get hotter and may need more air flow. I don't offer this information here for anyone to try it. You need to know what you're doing and what the tradeoffs are. I offer the info for the guy that "needs" 18 volts the easy way but sees mounting alternators under the hood as not an option.
Are you saying to connect the 6 volt battery to the vehicles 12 volt system?
If so when this is done you make the vehicles entire electrical system into an 18 supplied system and I'm not sure if some if not most of the vehicles electrical components will stand the higher voltage over the stock 12to 14 volts it's designed to operate at.